#153 - AMA #21: Deep dive into olive oil, high-intensity exercise, book update, and more

Mar 15, 2021 Episode Page ↗
Overview

The episode features Peter Atiyah and Bob Kaplan discussing olive oil's history, its link to the Mediterranean diet, and the classification of fats (SFA, MUFA, PUFA). It also previews other topics like Zone 5 training, standing desks, and electrolyte supplementation, which are covered in the full member-only AMA.

At a Glance
1 Insights
14m 2s Duration
7 Topics
6 Concepts

Deep Dive Analysis

Introduction to AMA #21 and Episode Topics

Initial Questions on Olive Oil's Health Benefits

Historical Context: Ancel Keys and the Mediterranean Diet

Early Research on Total Serum Cholesterol and Heart Disease

Evolution of the Saturated vs. Unsaturated Fat Hypothesis

Defining Saturated, Monounsaturated, and Polyunsaturated Fats

Chemical Structure and Nomenclature of Fatty Acids

Saturated Fats

These are long-chain fatty acids where all carbon-to-carbon bonds are single bonds, meaning each carbon atom is 'saturated' with hydrogen atoms. Their chains tend to be relatively straight in structure.

Monounsaturated Fats (MUFA)

These fats have one double bond within their carbon chain, making them 'less saturated' with hydrogens compared to saturated fats. This double bond introduces a slight 'crank' or bend in the fatty acid chain.

Polyunsaturated Fats (PUFA)

Characterized by having more than one double bond in their carbon chain, polyunsaturated fats are even more 'unsaturated' than monounsaturated fats. Multiple double bonds lead to multiple 'crinks' in their molecular structure.

Ancel Keys' Cholesterol Assay

In the 1950s, Ancel Keys developed one of the first methods to measure total serum blood cholesterol. This assay allowed for the quantification of all cholesterol carried by lipoproteins in the blood, which was a novel measurement at the time.

Fatty Acid Nomenclature

Fatty acids are chemically denoted by two numbers, such as '16:0' or '18:1'. The first number indicates the total count of carbon atoms in the chain, while the second number specifies the quantity of double bonds present.

Carboxylic Side

In the chemical nomenclature of fatty acids, the 'carboxylic side' refers to the specific end of the carbon chain from which counting begins to determine the position of double bonds. This standardized counting method ensures consistent identification of fatty acid structures.

?
Why is olive oil perceived as healthy and heart-protective?

The perceived health benefits of olive oil primarily stem from observational data related to the Mediterranean diet, which Ancel Keys began studying in the 1950s, linking diets high in monounsaturated fats to better heart health.

?
What are the three broad categories of dietary fats?

The three main categories of dietary fats are saturated fats, monounsaturated fats (MUFA), and polyunsaturated fats (PUFA), distinguished by the number of double bonds in their carbon chains.

?
How do saturated, monounsaturated, and polyunsaturated fats differ chemically?

Saturated fats have only single carbon-to-carbon bonds, making them 'saturated' with hydrogens and relatively straight. Monounsaturated fats have one double bond, creating a slight kink, while polyunsaturated fats have multiple double bonds, leading to more kinks in their structure and making them 'less saturated' with hydrogens.

?
How are fatty acids chemically named or denoted?

Fatty acids are denoted by two numbers, such as '16:0' or '18:1', where the first number indicates the total carbon count and the second indicates the number of double bonds. For unsaturated fats, an additional 'N' number specifies the position of the double bond, counting from the carboxylic side.

1. Seek Professional Medical Advice

Do not use the podcast content as a substitute for professional medical advice, diagnosis, or treatment; always seek assistance from your healthcare professionals for any medical conditions.

This is one of those topics, I think, like many others, where at the surface, it's pretty straightforward. But as is generally the theme of our podcast, the further you get from shore, the deeper the water gets.

Peter Attia

So you've got a long chain fatty acid is just, it's a string of carbon atoms... And depending on the number of carbons, that's in part how we classify it.

Bob Kaplan

And the nomenclature is not trivial.

Peter Attia
Early 1950s (specifically 1951, 1952, 1953)
Ancel Keys' travel and observation period When Keys and his wife traveled abroad to observe societies and measure serum blood cholesterol.
About 50 years ago
Timeframe for the idea of monounsaturated fats being heart-healthy When Ancel Keys started observing that diets high in monounsaturated fats were more heart-healthy than those high in saturated fats.
16:0
Palmitic acid carbon chain and double bonds Denotes 16 carbons and zero double bonds, classifying it as a saturated fat.
18:0
Stearic acid carbon chain and double bonds Denotes 18 carbons and zero double bonds, classifying it as a saturated fat.
18:1 N9
Oleic acid carbon chain, double bonds, and position Denotes 18 carbons, one double bond, with the double bond located at the ninth carbon from the carboxylic side, classifying it as a monounsaturated fat.